Aromatic C-H silylation of arenes with 1-hydrosilatrane catalyzed by an iridium(I)/2,9-dimethylphenanthroline (dmphen) complex.
نویسندگان
چکیده
Aromatic C-H silylation of neat arenes with 1-hydrosilatrane was found to be efficiently catalyzed by iridium catalysts composed of 1/2[Ir(OMe)(cod)]2 and 2,9-dimethyl-1,10-phenanthroline at 120 °C to afford the corresponding silylated products in high yields. The silylated products can be used for the Hiyama cross-coupling reaction.
منابع مشابه
Iridium-catalyzed borylation of arenes and heteroarenes via C–H activation*
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 11 47 شماره
صفحات -
تاریخ انتشار 2013